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71.
In this paper, we identify a crucial numerical problem in sigma coordinate models, leading to unacceptable spurious diapycnal mixing. This error is a by-product of recent advances in numerical methods, namely the implementation of high-order diffusive advection schemes. In the case of ROMS, spurious mixing is produced by its third-order upwind advection scheme, but our analysis suggests that all diffusive advection schemes would behave similarly in all sigma models. We show that the common idea that spurious mixing decreases with resolution is generally false. In a coarse-resolution regime, spurious mixing increases as resolution is refined, and may reach its peak value when eddy-driven lateral mixing becomes explicitly resolved. At finer resolution, diffusivities are expected to decrease but with values that only become acceptable at resolutions finer than the kilometer. The solution to this problem requires a specifically designed advection scheme. We propose and validate the RSUP3 scheme, where diffusion is split from advection and is represented by a rotated biharmonic diffusion scheme with flow-dependent hyperdiffusivity satisfying the Peclet constraint. The rotated diffusion operator is designed for numerical stability, which includes improvements of linear stability limits and a clipping method adapted to the sigma-coordinate. Realistic model experiments in a southwest Pacific configuration show that RSUP3 is able to preserve low dispersion and diffusion capabilities of the original third-order upwind scheme, while preserving water mass characteristics. There are residual errors from the rotated diffusion operator, but they remain acceptable. The use of a constant diffusivity rather than the Peclet hyperdiffusivity tends to increase these residual errors which become unacceptable with Laplacian diffusion. Finally, we have left some options open concerning the use of time filters as an alternative to spatial diffusion. A temporal discretization approach to the present problem (including implicit discretization) will be reported in a following paper.  相似文献   
72.
73.
The new target of the Rosetta mission is comet 67P/Churyumov-Gerasimenko (hereafter 67P/C-G). In order to support the planning of the mission, in particular the strategy during the mapping and landing phases, we have performed numerical simulations of the rotational evolution of a comet in the orbit of 67P/C-G. In these simulations, the currently known observational constraints have been taken into account and a large set of initial conditions were considered. For most of the simulations, we observe that the sublimation-induced torques produce significant changes in the rotational parameters of a 67P/C-G-like comet. Typical rates of change for the spin period from the rendezvous up to the end of the nominal mission range from 0.001 to depending on different circumstances as described in the text. At perihelion, rates of change of the orientation of the angular momentum vector amount to about 0.01-. These simulations suggest that a specific strategy should be defined in order to monitor likely variations of the rotational parameters. As an example we show a possible optimized schedule for observations with the OSIRIS instrument to determine the rotational parameters of comet 67P/C-G and their possible evolution.  相似文献   
74.
The surface ocean explains a considerable part of the inter-annual Tropical Atlantic variability. The present work makes use of observational datasets to investigate the effect of freshwater flow on sea surface salinity (SSS) and temperature (SST) in the Gulf of Guinea. In particular, the Congo River discharges a huge amount of freshwater into the ocean, affecting SSS in the Eastern Equatorial Atlantic (EEA) and stratifying the surface layers. The hypothesis is that an excess of river runoff emphasize stratification, influencing the ocean temperature. In fact, our findings show that SSTs in the Gulf of Guinea are warmer in summers following an anomalously high Congo spring discharge. Vice versa, when the river discharges low freshwater, a cold anomaly appears in the Gulf. The response of SST is not linear: temperature anomalies are considerable and long-lasting in the event of large freshwater flow, while in dry years they are less remarkable, although still significant. An excess of freshwater seems able to form a barrier layer, which inhibits vertical mixing and the entrainment of the cold thermocline water into the surface. Other processes may contribute to SST variability, among which the net input of atmospheric freshwater falling over EEA. Likewise the case of continental runoff from Congo River, warm anomalies occur after anomalously rainy seasons and low temperatures follow dry seasons, confirming the effect of freshwater on SST. However, the two sources of freshwater anomaly are not in phase, so that it is possible to split between atypical SST following continental freshwater anomalies and rainfall anomalies. Also, variations in air-sea fluxes can produce heating and cooling of the Gulf of Guinea. Nevertheless, atypical SSTs cannot be ascribed to fluxes, since the temperature variation induced by them is not sufficient to explain the SST anomalies appearing in the Gulf after anomalous peak discharges. The interaction processes between river runoff, sea surface salinity and temperature play an effective role in the interannual variability in the EEA region. Our results add a new source of variability in the area, which was often neglected by previous studies.  相似文献   
75.
Although GNSS techniques are theoretically sensitive to the Earth center of mass, it is often preferable to remove intrinsic origin and scale information from the estimated station positions since they are known to be affected by systematic errors. This is usually done by estimating the parameters of a linearized similarity transformation which relates the quasi-instantaneous frames to a long-term frame such as the International Terrestrial Reference Frame (ITRF). It is well known that non-linear station motions can partially alias into these parameters. We discuss in this paper some procedures that may allow reducing these aliasing effects in the case of the GPS techniques. The options include the use of well-distributed sub-networks for the frame transformation estimation, the use of site loading corrections, a modification of the stochastic model by downweighting heights, or the joint estimation of the low degrees of the deformation field. We confirm that the standard approach consisting of estimating the transformation over the whole network is particularly harmful for the loading signals if the network is not well distributed. Downweighting the height component, using a uniform sub-network, or estimating the deformation field perform similarly in drastically reducing the amplitude of the aliasing effect. The application of these methods to reprocessed GPS terrestrial frames permits an assessment of the level of agreement between GPS and our loading model, which is found to be about 1.5 mm WRMS in height and 0.8 mm WRMS in the horizontal at the annual frequency. Aliased loading signals are not the main source of discrepancies between loading displacement models and GPS position time series.  相似文献   
76.
Climate models suggest that anthropogenic emissions are likely to induce an important drying during summer over most of Europe in the late 21st century. However, the amplitude of the associated decrease in precipitation strongly varies among the different climate models. In order to reduce this spread, it is first necessary to identify its causes and the associated physical mechanisms. Consequently, the focus of this paper is to better estimate the role of large scale circulation (LSC) in precipitation changes over Europe using a multi-model framework and then to characterize the LSC changes using the weather regime paradigm. We show that LSC changes directly lead to a decrease of precipitation over northwestern Europe. This circulation-driven decrease in rainfall is mainly linked to an increase (decrease) of the occurrence of positive (negative) phase of the North Atlantic Oscillation regime. LSC is also responsible for a significant part of the models spread in precipitation changes over these regions. Over southern Europe, the role of LSC changes on multi-model mean precipitation changes is generally weak. We also show that the precipitation anomalies directly induced by LSC modifications seem to be further amplified through local feedbacks.  相似文献   
77.
Thermodynamic calculations and Gibbs free energy minimization computer experiments strongly support the hypothesis that kerogen maturation and oil generation are inevitable consequences of oxidation/reduction disproportionation reactions caused by prograde metamorphism of hydrocarbon source rocks with increasing depth of burial.These experiments indicate that oxygen and hydrogen are conserved in the process.Accordingly, if water is stable and present in the source rock at temperatures ?25 but ?100 °C along a typical US Gulf Coast geotherm, immature (reduced) kerogen with a given atomic hydrogen to carbon ratio (H/C) melts incongruently with increasing temperature and depth of burial to produce a metastable equilibrium phase assemblage consisting of naphthenic/biomarker-rich crude oil, a type-II/III kerogen with an atomic hydrogen/carbon ratio (H/C) of ∼1, and water. Hence, this incongruent melting process promotes diagenetic reaction of detritus in the source rock to form authigenic mineral assemblages.However, in the water-absent region of the system CHO (which is extensive), any water initially present or subsequently entering the source rock is consumed by reaction with the most mature kerogen with the lowest H/C it encounters to form CO2 gas and a new kerogen with higher H/C and O/C, both of which are in metastable equilibrium with one another.This hydrolytic disproportionation process progressively increases both the concentration of the solute in the aqueous phase, and the oil generation potential of the source rock; i.e., the new kerogen can then produce more crude oil.Petroleum is generated with increasing temperature and depth of burial of hydrocarbon source rocks in which water is not stable in the system CHO by a series of irreversible disproportionation reactions in which kerogens with higher (H/C)s melt incongruently to produce metastable equilibrium assemblages consisting of crude oil, CO2 gas, and a more mature (oxidized) kerogen with a lower H/C which in turn melts incongruently with further burial to produce more crude oil, CO2 gas, and a kerogen with a lower H/C and so forth.The petroleum generated in the process progresses from heavy naphthenic crude oils at low temperatures to mature petroleum at ∼150 °C. For example, the results of Computer Experiment 27 (see below) indicate that the overall incongruent melting reaction in the water-absent region of the system C-H-O at 150 °C and a depth of ∼4.3 km of an immature type-II/III kerogen with a bulk composition represented by C292H288O12(c) to produce a mature (oxidized) kerogen represented by C128H68O7(c), together with a typical crude oil with an average metastable equilibrium composition corresponding to C8.8H16.9 (C8.8H16.9(l)) and CO2 gas (CO2(g)) can be described by writing
(A)  相似文献   
78.
Recent data on He diffusion challenge the temperature sensitivity of apatite (U–Th)/He thermochronology: the damage induced by recoil of U and Th decay series during emission of α particles (α-recoil damage) has been proposed to modify He-diffusion properties through time. However, we propose that annealing of these irradiation defects may be an important phenomenon and may be significant in case of slowly-cooled or reheated basement rocks. To test this hypothesis, we developed a quantitative model including an explicit treatment of α-recoil damage, annealing, and their effect on He-diffusion kinetics, and calibrate it against literature data. Our model is based on two hypotheses: (1) helium is in equilibrium between an apatite crystal and its defects and (2) alpha-recoil damage annealing can be described analogously to fission-track annealing. This model has been embedded into a Monte Carlo simulation of helium production/ejection/diffusion and applied to data from the French Massif Central; a complex slowly-cooled terrain with burial reheating, where the thermal history has been constrained by previous fission-track (FT) data including FT length distributions. (U–Th)/He ages are close to the FT ages from the same samples and are generally reproducible among replicates, but some samples present He-age dispersion that is not correlated with crystal size. Our model reproduces the Massif Central data very well except for three samples where He ages are older than corresponding FT ages. We show that annealing of irradiation damage has an important impact on retentivity of helium and that the He content, [He] is only a rough approximation of the damage level. In particular our results show that independence of He ages on crystal sizes, in case of reheated samples, is a clear indication of the higher He retentivity induced by α-recoil defects and that an explicit treatment of defect annealing is required for a correct interpretation of (U–Th)/He ages in such a case. More generally a correlation with the crystal size can bring information on the thermal path only if the age of defects, well represented by the fission-track age, is available, due to the dependence of the partial retention zone on damages. Conversely, in case of rapid cooling or for samples having low U and Th contents, damage effects can be ignored without significant effects on He ages.  相似文献   
79.
GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   
80.
Abstract— Kainsaz CO3 insoluble organic matter (IOM) was studied using Curie point pyrolysis, electronic paramagnetic resonance (EPR), and high‐resolution transmission electron microscopy (HRTEM) to determine the effect of thermal metamorphism on molecular chondritic fingerprints. Pyrolysis released a very low amount of products that consist of one‐ and two‐ring aromatic units with methyl, dimethyl, and ethyl substituents. Moreover, Kainsaz IOM contains two orders of magnitude fewer radicals than Orgueil, Murchison, and Tagish Lake IOM. In addition, no diradicaloids were found in Kainsaz, although they are thought to constitute a specific signature for weakly organized extraterrestrial organic compounds in contrast to terrestrial ones. HRTEM reveals a very heterogeneous structure, with microporous disordered carbon, mesoporous graphitic carbons and graphite. Graphitization likely occurs and explains the differences between Kainsaz and CI or CM IOM. Heating stress experienced by Kainsaz IOM, on the parent body and/or prior its accretion, is likely responsible for the differences in molecular and structural organizations compared with those of CI and CM IOM.  相似文献   
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